Answer
The circle (or otherwise white mark) is a meant to be a reflection.
The reflection makes it more realistic and understandable as an icon. As seen in a google image search, our eyes are pretty reflective and we often perceive this even if we don’t consciously think about it. As Andrew H notes, this reflection is called a catch light. Below is one for example:
For comparison take a look at these two icons below. I’d argue that the one with the dot looks more human like and friendly.
Attribution
Source : Link , Question Author : Altaf , Answer Author : Community